Chapter 15: Strong Field Excitation

Calculation of the evolution of the population in a 3-level A system using the STIRAP scheme (dressed state representation).
Consider the 3-level system shown in the figure below:
The Actual Scheme
In the rotating frame and making the RWA the Hamiltonian can be written:
The Actual Formula
with The Actual Formula This matrix can be diagonalized yielding the eigenvalues,
The Actual Formula
and eigenvectors
The Actual Formula
Where The Actual Formula The eigenvectors The Actual Formula are dressed states, i.e. eigenfunctions of the instantaneous Hamiltonian in the presence of the fields. Consider the adiabatic change in field intensities such that for The Actual Formula while for The Actual Formula This adiabatic transformation will leave the system in the dressed state The Actual Formula while changing its character from that of level |1> to that of level |3>. Since the dressed state The Actual Formula contains no component of level |2>, this adiabatic change leads to complete population transfer from level |1> to level |3>, without populating level |2>. This is the basis for the remarkable Stimulated Raman Adiabatic Passage (STIRAP) scheme. Note the counterintuitive order of the pulses, i.e. The Actual Formula precedes The Actual Formula.