T. H. Reingewertz, M. Ben-Maimon, Z. Zafrir, T. Tuller and A. Horovitz (2024)
Synonymous and non-synonymous codon substitutions can alleviate dependence on GroEL for folding
Protein Sci. 33, e5087. https://onlinelibrary.wiley.com/doi/full/10.1002/pro.5087
M. Roy, R. C. Fleisher, A. I. Alexandrov and A. Horovitz (2023)
Reduced ADP off-rate by the yeast CCT2 double mutation T394P/R510H which causes Leber congenital amaurosis in humans
Commun. Biol. 6, 888. https://www.nature.com/articles/s42003-023-05261-8
D. G. Liebermann, J. Jungwirth, I. Riven, Y. Barak, D. Levy, A. Horovitz, G. Haran (2023)
From microstates to macrostates in the conformational dynamics of GroEL: a single-molecule FRET study
J. Phys. Chem. Lett. 14, 6513-6521. https://pubmed.ncbi.nlm.nih.gov/37440608/
2022
I. Korobko, R. B. Eberle, M. Roy and A. Horovitz (2022)
A diminished hydrophobic effect inside the GroEL/ES cavity contributes to protein substrate destabilization.
Proc. Natl. Acad. Sci. U. S. A. 119, e2213170119. https://pubmed.ncbi.nlm.nih.gov/36409898/
J. Singh, R. Anand, A. Horovitz (2022)
Cooperatively in ATP hydrolysis by MopR is modulated by its signal reception domain and by its protein and phenol concentrations
J. Bacteriol. 204,e0017922. https://pubmed.ncbi.nlm.nih.gov/35862728/
M. Roy and A. Horovitz (2022)
Partitioning the Hill coefficient into contributions from ligand-promoted conformational changes and subunit heterogeneity
Protein Sci. 31, e4298. https://onlinelibrary.wiley.com/doi/10.1002/pro.4298
A. Horovitz*, T. H. Reingewertz, J. Cuéllar and J. M. Valpuesta* (2022)
Chaperonin mechanisms: multiple and (mis)understood?
Annu. Rev. Biophys. 51, 115-133.
(*corresponding authors) https://pubmed.ncbi.nlm.nih.gov/34982571/
2021
S. J. Fleishman and A. Horovitz (2021)
Extending the new generation of structure predictors to account for dynamics and allostery
J. Mol. Biol. 433, 167007. https://pubmed.ncbi.nlm.nih.gov/33901536/
N. Macro, L. Chen, Y. Yang, T. Mondal, L. Wang, A. Horovitz* and D. Zhong* (2021)
Slowdown of water dynamics from the top to the bottom of the GroEL cavity
J. Phys. Chem. Lett. 12, 5723-5730.
(*corresponding authors) https://pubs.acs.org/doi/abs/10.1021/acs.jpclett.1c01216
A. Horovitz and T. Mondal (2021)
Discriminating between concerted and sequential allosteric mechanisms by comparing equilibrium and kinetic Hill coefficients.
J. Phys. Chem. B 125, 70-73. https://pubs.acs.org/doi/10.1021/acs.jpcb.0c09351
2020
J. Cveticanin, T. Mondal, E. M. Meiering, M. Sharon and A. Horovitz (2020)
Insight into the autosomal-dominant inheritance pattern of SOD1-associated ALS from native mass spectrometry.
J. Mol. Biol.432, 5995-6002. www.sciencedirect.com/science/article/pii/S0022283620305817
I. Korobko, H. Mazal, G. Haran and A. Horovitz (2020)
Measuring protein stability in the GroEL chaperonin cage reveals massive destabilization.
eLife 9, e56511. elifesciences.org/articles/56511
L. S. Bigman and A. Horovitz (2019)
Reconciling the controversy regarding the functional importance of bullet- and football-shaped GroE complexes.
J. Biol. Chem. 294, 13527-135279. http://www.jbc.org/content/294/37/13527
S. J. Wodak, E. Paci, N. V. Dokholyan, I. N. Berezovsky, A. Horovitz, J. Li, V. J. Hilser, I. Bahar, J. Karanicolas, G. Stock, P. Hamm, R. H. Stote, J. Eberhardt, Y. Chebaro, A. Dejaegere, M. Cecchini, J.-P. Changeux, D. Keri, P. Barth, P. G. Bolhuis, J. Vreede, P. Faccioli, S. Orioli, R. Ravasio, L. Yan, C. Brito, M. Wyart, P. Gkeka, I. Rivalta, G. Palermo, J. A. McCammon, J. Panecka-Hofman, R. C. Wade, A. Di Pizio, M. Y. Niv, R. Nussinov, C.-J. Tsai, H. Jang, D. Padhorny, D. Kozakov, T. McLeish (2019)
Allostery in its many disguises: from theory to applications
Structure 27, 566-578. https://www.sciencedirect.com/science/article/pii/S0969212619300036?via%3Dihub
J. Cveticanin, R. Netzer, G. Arkind, S. J. Fleishman, A. Horovitz* and M. Sharon* (2018)
Estimating interprotein pairwise interaction energies in cell lysates from a single native mass spectrum.
Anal. Chem. 90, 10090-10094.
(*corresponding authors) https://pubs.acs.org/doi/10.1021/acs.analchem.8b02349
B. Bandyopadhyay, A. Goldenzweig, T. Unger, O. Adato, S. J. Fleishman, R. Unger and A. Horovitz (2017)
Local energetic frustration affects the dependence of GFP folding on the chaperonin GroEL
J. Biol. Chem. 292, 20583-20591. http://www.jbc.org/content/early/2017/10/24/jbc.M117.808576.full.pdf
R. Gruber, M. Levitt and A. Horovitz (2017)
Sequential allosteric mechanism of ATP hydrolysis by the CCT/TRiC chaperone is revealed through Arrhenius analysis
Proc. Natl. Acad. Sci. U. S. A. 114, 5189-5194. http://www.pnas.org/content/114/20/5189.long
M. Sokolovski, J. Cveticanin, D. Hayoun, I. Korobko, M. Sharon and A. Horovitz (2017)
Measuring inter-protein pairwise interaction energies from a single native mass spectrum by double-mutant cycle analysis
Nat. Commun. 8, 212. http://rdcu.be/uRI4
2016
I. Korobko, M. Nadler-Holly and A. Horovitz (2016)
Transient kinetic analysis of ATP hydrolysis by the CCT/TRiC chaperonin
J. Mol. Biol. 428, 4520-4527. https://www.ncbi.nlm.nih.gov/pubmed/27686496
W. Mao, C. Kaya, A. Dutta, A. Horovitz and I. Bahar (2015)
Comparative study of the effectiveness and limitations of current methods for detecting sequence coevolution
Bioinformatics 31, 1929-1937. http://www.ncbi.nlm.nih.gov/pubmed/25697822
E. Jacob, R. Unger and A. Horovitz (2015)
Codon-level information improves predictions of inter-residue contacts in proteins by correlated mutation analysis
eLife 4, e08932. https://elifesciences.org/content/4/e08932
J. Franck, M. Sokolovski, N. Kessler, E. Matalon, M. Gordon-Grossman, S. Han, D. Goldfarb and A. Horovitz (2014)
Probing water density and dynamics in the chaperonin GroEL cavity
J. Amer. Chem. Soc. 136, 9396-9403. http://pubs.acs.org/doi/abs/10.1021/ja503501x
O. Matalon, A. Horovitz and E. D. Levy (2014)
Different subunits belonging to the same protein complex often exhibit discordant expression levels and evolutionary properties
Curr. Opin. Struct. Biol. 26, 113-120. http://www.sciencedirect.com/science/article/pii/S0959440X14000645
A. Dyachenko, R. Gruber, L. Shimon, A. Horovitz* and M. Sharon* (2013)
Allosteric mechanisms can be distinguished using structural mass spectrometry
Proc. Natl. Acad. Sci. U. S. A. 110, 7235-7239.
(*corresponding authors) http://www.pnas.org/content/110/18/7235.long
A. Horovitz (2013)
Double-mutant cycle analysis
In: Encyclopedia of Biophysics (Roberts, G. C. K., ed.), pp. 510-512 (Springer-Verlag, Berlin
2012
H. M. Piwonski, M. Goomanovsky, D. Bensimon, A. Horovitz and G. Haran (2012)
Allosteric inhibition of individual enzyme molecules trapped in lipid vesicles
Proc. Natl. Acad. Sci. U. S. A. 109, E1437-E1443. http://www.pnas.org/content/109/22/E1437.long
M. Nadler-Holly, M. Breker, R. Gruber, A. Azia, M. Gymrek, M. Eisenstein, K. R. Willison, M. Schuldiner and A. Horovitz (2012)
Interactions of subunit CCT3 in the yeast chaperonin CCT/TRiC with Q/N-rich proteins
revealed by high-throughput microscopy analysis
Proc. Natl. Acad. Sci. U. S. A. 109, 18833-18838. http://www.pnas.org/content/109/46/18833.long
M. Amit, S. J. Weisberg, M. Nadler-Holly, E. A. McCormack, E. Feldmesser, D. Kaganovich, K. R. Willison and A. Horovitz (2010)
Equivalent mutations in the eight subunits of the eukaryotic chaperonin CCT produce dramatically different cellular and gene expression phenotypes
J. Mol. Biol. 401, 532-543. http://www.sciencedirect.com/science/article/pii/S0022283610006686
L. Shimon, M. Sharon and A. Horovitz (2010)
A method for removing effects of non-specific binding on the distribution of binding stochiometries: application to mass spectroscopy data
Biophys. J. 99, 1645-1649. http://www.ncbi.nlm.nih.gov/pubmed/20816078
G. A. Frank, M. Goomanovsky, A. Davidi, G. Ziv, A. Horovitz* and G. Haran* (2010)
Out-of-equilibrium conformational cycling of GroEL at saturating ATP concentrations
Proc. Natl. Acad. Sci. U. S. A. 107, 6270-6274.
(*corresponding authors) http://www.pnas.org/content/107/14/6270.long
A. Parnas, M. Nadler, S. Nisemblat, A. Horovitz*, H. Mandel and A. Azem* (2009)
The MitCHAP-60 disease is due to entropic destabilization of the human mitochondrial hsp60 oligomer
J. Biol. Chem. 284, 28198-28203.
(*corresponding authors) http://www.jbc.org/content/284/41/28198.long
O. Noivirt-Brik, A. Horovitz* and R. Unger (2009)
Trade-off between positive and negative design of protein stability: from lattice models to real proteins
PLoS Comput. Biol. 5, e1000592.
(*corresponding author) http://www.ncbi.nlm.nih.gov/pubmed/20011105
2008
L. Shimon, G. M. Hynes, E. A. McCormack, K. R. Willison and A. Horovitz (2008)
ATP-induced allostery in the eukaryotic chaperonin CCT is abolished by the mutation
G345D in CCT4 that renders yeast temperature-sensitive for growth
J. Mol. Biol. 377, 469-477. http://www.sciencedirect.com/science/article/pii/S0022283608000296
N. Papo, Y. Kipnis, G. Haran and A. Horovitz (2008)
Concerted release by ATP of individual domains of a protein substrate of GroEL is demonstrated with FRET
J. Mol. Biol. 380, 717-725. http://www.ncbi.nlm.nih.gov/pubmed/18556021
G. A. Frank, Y. Kipnis, E. Smolensky, S. S. Daube, A. Horovitz and G. Haran (2008)
Design of an optical switch for studying conformational dynamics in individual molecules of GroEL
Bioconjugate Chem. 19, 1339-1341. http://pubs.acs.org/doi/abs/10.1021/bc800118j
2007
F. Naider, J. M. Becker, Y. -H. Lee and A. Horovitz (2007)
Double-mutant cycle scanning of the interaction of a peptide ligand and its G protein-coupled receptor
Biochemistry 46, 3476-3481. http://pubs.acs.org/doi/abs/10.1021/bi602415u
Y. Kipnis, N. Papo, G. Haran and A. Horovitz (2007)
Concerted ATP-induced allosteric transitions in GroEL facilitate release of protein substrate domains in an all-or-none manner
Proc. Natl. Acad. Sci. U. S. A. 104, 3119-3124. http://www.pnas.org/content/104/9/3119.long
O. Noivirt-Brik, R. Unger and A. Horovitz (2007)
Low folding propensity and high translation efficiency distinguish in vivo substrates of GroEL from other E. coli proteins
Bioinformatics 23, 3276-3279. http://bioinformatics.oxfordjournals.org/content/23/24/3276.long
D. Rivenzon-Segal, S. G. Wolf, L. Shimon, K. R. Willison and A. Horovitz (2005)
Sequential ATP-induced allosteric transitions of the cytoplasmic chaperonin containing TCP-1 revealed by EM analysis
Nat. Struct. Mol. Biol. 12, 233-237. http://www.nature.com/nsmb/journal/v12/n3/full/nsmb901.html
O. Noivirt, M. Eisenstein and A. Horovitz (2005)
Detection and reduction of evolutionary noise in correlated mutation analysis
Protein Eng. Des. Sel. 18, 247-253. http://peds.oxfordjournals.org/content/18/5/247.long
O. Danziger, D. Rivenzon-Segal, S. G. Wolf and A. Horovitz (2003)
Conversion of the allosteric transition of GroEL from concerted to sequential by the single mutation Asp-155®Ala
Proc. Natl. Acad. Sci. U. S. A. 100, 13797-13802. http://www.pnas.org/content/100/24/13797.long
2002
Y. Fridmann, G. Kafri, O. Danziger and A. Horovitz (2002)
Dissociation of the GroEL-GroES asymmetric complex is accelerated by increased cooperativity in ATP binding to the GroEL ring distal to GroES
Biochemistry 41, 5938-5944. http://pubs.acs.org/doi/abs/10.1021/bi020117v
A. Horovitz, A. Amir, O. Danziger and G. Kafri (2002)
Φ-value analysis of heterogeneity in pathways of allosteric transitions: evidence for parallel pathways of ATP-induced conformational changes in a GroEL ring
Proc. Natl. Acad. Sci. U. S. A. 99, 14095-14097. http://www.pnas.org/content/99/22/14095.long
O. Yifrach and A. Horovitz (2000)
Coupling between protein folding and allostery in the GroE chaperonin system
Proc. Natl. Acad. Sci. U. S. A. 97, 1521-1524. http://www.pnas.org/content/97/4/1521.long
A. Horovitz and O. Yifrach (2000)
On the relationship between the Hill coefficients for steady-state and transient kinetic data: a criterion for concerted transitions in allosteric proteins
Bull. Math. Biol. 62, 241-246.
Y. Fridmann, S. Ulitzur and A. Horovitz (2000)
In vivo and in vitro function of GroEL mutants with impaired allosteric properties
J. Biol. Chem. 275, 37951-37956. http://www.jbc.org/content/275/48/37951.long
O. Yifrach and A. Horovitz (1998)
Transient kinetic analysis of adenosine 5'-triphosphate binding-induced conformational changes in the allosteric chaperonin GroEL
Biochemistry 37, 7083-7088. http://pubs.acs.org/doi/abs/10.1021/bi980370o
A. Aharoni and A. Horovitz (1997)
Detection of changes in pairwise interactions during allosteric transitions: coupling between local and global conformational changes in GroEL
Proc. Natl. Acad. Sci. U. S. A. 94, 1698-1702. http://www.pnas.org/content/94/5/1698.long
H. E. White, S. Chen, A. M. Roseman, O. Yifrach, A. Horovitz and H. R. Saibil (1997)
Structural basis of allosteric changes in the GroEL mutant Arg197→Ala
Nat. Struct. Biol. 4, 690-694. http://www.nature.com/nsmb/journal/v4/n9/abs/nsb0997-690.html
E. Inbar and A. Horovitz (1997)
GroES promotes the T to R transition of the GroEL ring distal to GroES in the GroEL-GroES complex
Biochemistry 36, 12276-12281. http://pubs.acs.org/doi/abs/10.1021/bi9714870
G. A. Faiman and A. Horovitz (1997)
Thermodynamic analysis of the interaction between the 0.5ß Fv fragment and the RP135 peptide antigen derived from the V3 loop of HIV-1 gp120
J. Biol. Chem. 272, 31407-31411. http://www.jbc.org/content/272/50/31407.long
G. A. Faiman and A. Horovitz (1996)
On the choice of reference mutant states in the application of the double-mutant cycle method
Protein Eng. 9, 315-316. http://peds.oxfordjournals.org/content/9/3/315.long
G. A. Faiman, R. Levy, J. Anglister and A. Horovitz (1996)
Contribution of arginine residues in the RP135 peptide derived from the V3 loop of gp120 to its interaction with the Fv fragment of the 0.5ß HIV-1 neutralizing antibody
J. Biol. Chem. 271, 13829-13833. http://www.jbc.org/content/271/23/13829.long
1995
A. Horovitz (1995)
The relation between co-operativity in ligand binding and intramolecular co‑operativity in allosteric proteins
Proc. R. Soc. London Ser. B 259, 85-87.
E. S. Bochkareva, A. Horovitz and A. S. Girshovich (1994)
Direct demonstration that ATP is in contact with Cys-137 in chaperonin GroEL
J. Biol. Chem. 269, 44-46. http://www.jbc.org/content/269/1/44.long
A. Horovitz, E. S. Bochkareva, O. Yifrach and A. S. Girshovich (1994)
Prediction of an inter-residue interaction in the chaperonin GroEL from multiple sequence alignment is confirmed by double-mutant cycle analysis
J. Mol. Biol. 238, 133-138. http://www.sciencedirect.com/science/article/pii/S0022283684712757
D. Lancet, A. Horovitz and E. Katchalski-Katzir (1994)
Molecular recognition in biology: models for analysis of protein-ligand interactions
In: 100 Years of the Lock-and-Key Principle (Behr, J. -P., ed.), pp. 25-71 (J. Wiley, NY)
A. Horovitz, E. S. Bochkareva and A. S. Girshovich (1993)
The N terminus of the molecular chaperonin GroEL is a crucial structural element for its assembly
J. Biol. Chem. 268, 9957-9959. http://www.jbc.org/content/268/14/9957.long
C. Sander, G. Vriend, F. Bazan, A. Horovitz, H. Nakamura, L. Ribas, A. V. Finkelstein, A. Lockhart, R. Merkl, L. J. Perry, S. C. Emery, C. Gaboriaud, C. Marks, J. Moult, C. Verlinde, M. Eberhard, A. Elofsson, T. J. P. Hubbard, L. Regan, J. Banks, R. Jappelli, A. M. Lesk and A. Tramontano (1992)
Protein design on computers. Five new proteins: Shpilka, Grendel, Fingerclasp, Leather and Aida
Proteins: Struct. Funct. & Genet. 12, 105-110. http://onlinelibrary.wiley.com/doi/10.1002/prot.340120203/abstract
A. Horovitz, L. Serrano, B. Avron, M. Bycroft and A. R. Fersht (1990)
Strength and co-operativity of contributions of surface salt bridges to protein stability Appendix: Interpretation of coupling energies in multiple thermodynamic cycles of mutants
J. Mol. Biol. 216, 1031-1044. http://www.sciencedirect.com/science/article/pii/S0022283699800187
M. Rigbi, H. Levy, F. Iraqi, M. Teitelbaum, M. Orevi, A. Alajoutsijarvi, A. Horovitz and R. Galun (1987)
The saliva of the medicinal leech Hirudo medicinalis I. Biochemical characterization of the high molecular weight fraction
Comp. Biochem. Physiol. 87B, 567-573.
M. Rigbi, H. Levy, A. Eldor, F. Iraqi, M. Teitelbaum, M. Orevi, A. Horovitz and R. Galun (1987)
The saliva of the medicinal leech Hirudo medicinalis II. Inhibition of platelet aggregation and of leukocyte activity and examination of reputed anaesthetic effects
Comp. Biochem. Physiol. 88C, 95-98.
A. Horovitz and A. Levitzki (1987)
An accurate method for the determination of receptor-ligand and enzyme-inhibitor dissociation constants from displacement curves
Proc. Natl. Acad. Sci. U. S. A. 84, 6654-6658. http://www.pnas.org/content/84/19/6654.long
1986
A. Horovitz (1986)
Measures of cooperativity in the binding of ligands to proteins and their relation to non‑additivity in protein-protein interactions
Proc. R. Soc. London Ser. B 229, 315-329.