Cancelled : Light-matter interaction from the photon perspective
Cancelled: In this discussion, we will take least conventional route to look at light-matter interaction from perspective of light, rather than conventional view as it is dictated solely by the material. Obviously, every optical process is a light–matter interaction, hence the transition probability is equally a property of the electromagnetic field itself. We will show that by shaping, confining, or conditioning the optical field, even in simple experimental configurations, one can fundamentally alter light–matter interactions and induce dramatic changes in optical behavior. First, using silicon as a model system, we illustrate how engineered multi-photon processes enable broadband detection across a multi-octave spectral range, including label-free, chemically specific IR tomography and high-speed hyperspectral IR video imaging. Second, we introduce a new photonic phenomenon that stems directly from the Heisenberg uncertainty principle governing the spatial and momentum degrees of freedom. When light is confined to sub-2 nm dimensions, its momentum becomes comparable to that of electrons in solids. Under these conditions, photons acquire de Broglie wavelengths capable of matching electronic states, greatly enhancing optical transition rates - a regime previously associated only with X-ray photons in classical Compton scattering. This overlooked photonic mechanism opens a new pathway for manipulating optical transitions, with profound implications for semiconductor physics and photonic technologies.